Road Brine- Why you need Rust inhibitors for cars or trucks

Your car — an investment second only to your home (unless you’ve paid college tuition) — is rotting out from under you.

Road brine is a treatment for the highways and local roads of the nation, especially those that experience sub-zero temperatures in the winter. It stops us slipping and sliding when out and about taking our children to school or commuting to work. But there is a hidden cost to using road brine. One that brings the need for rust inhibitors for cars and trucks or oil-based rustproofing to the fore. And the problem is literally eating away at the underside of many cars, trucks and other vehicles across the USA – and the rest of the worldat the underside of many cars, trucks and other vehicles across the USA – and the rest of the world.Road brine and rust inhibitors

Road brine looks like quite a natural solution to keeping the roads safe. It used salt and water – the combination known as brine – to stop the road from freezing and provide conditions that are safe to drive in. You may spend time looking after your car on the inside and the bodywork all year around. You will even get that winter check before the cold really starts to kick in to make sure you are on top of the maintenance of your vehicle. But I bet you have never considered oil-based rustproofing with rust inhibitors for cars and trucks to solve a problem .

Road brine eats away at the underside of your vehicle.Car rust and corrosion are caused by acid created when a salt is dissolved by the moisture in the air. Rock salt remains a crystal until the humidity reaches 70 percent, which doesn’t happen much during the winter. But magnesium chloride dissolves when there is only about 20 to 30 percent humidity. “Which means that your vehicle, if magnesium chloride is sprayed on it, is wet constantly,” Baboian said. The acid stays on your car and slowly eats away at the paint and metal.undercoating truck car Rust inhibitors

The salt accelerates the oxidation on metal chassis and starts a rusting process that accelerates every time you take the car out in theses conditions. Let’s face it – for many of us there is no choice but to use our vehicle day after day. When we do, the salt sits there, unwashed, and corrodes. The risk is worsened performance and a safety problem that you can’t see unfolding. There is a huge worry in this, as corrosion from road brine is linked to tens of thousands of accidents across the United States. Examples can be found all over.

The other issue with road brine is the fact that magnesium is added to the mix, in small quantities. Although there isn’t much, it stops the vehicle from drying out, leaving the acidity from the salt to do a lot of harm to your car. You should look at how you can address this to prolong the life of your vehicle and to stay safe on the road.

If you are a business owner, then you want your employees and all in the vehicle to stay safe.

If you are a car owner, then you use your vehicle to transport all that is important to you.

Either way, there is a huge incentive to look into oil-based rustproofing with rust inhibitors for cars and trucks or oil-based rustproofing as a solution to this problem. Let’s take a look at what these items mean in reality.

 

Rust inhibitors for cars and trucks – what are they all about?

Inhibitors classifications Corrosion inhibitors for cars and trucks

The corrosion inhibitors can be chemicals either synthetic or natural and could be classified

Figure 1. Classification of inhibitors

by: 

  • the chemical nature as organic or inorganic;
  • the mechanism of action as anodic, cathodic or a anodic-cathodic mix and by adsorption

action, or; as oxidants or not oxidants. 

In general, the inorganic inhibitors have cathodic actions or anodic. The organics inhibitors

have both actions, cathodic and anodic and the protective by a film adsorption.

This chapter is subdivided in according to the classification of the inhibitors shown on the

 

Rust inhibitors for cars or trucks are chemical compounds that are added to other liquids in a vehicle to aid the protection against rust. They can work from the inside or outside to stop rust at source. There are some that can be added to gas or oil to stop oxidization inside the engine. But that is a tiny part of the problem and these don’t look at the real issue.

The underside of a vehicle is where the corrosion happens and causes the concerning damage. So, the majority of rust inhibitors for cars and trucks are sprays that can be applied on a regular basis. There are scores of them available here and these can be bought at a relatively small cost. The recommendation is that these are carried out annually at least, with the Spring months being the ideal point in time to apply this spray. This leaves the car protected in some way, so think about how you can make all of this happen.

Fortunately,  this approach can be accomplished by a do-it-your-selfer here is a How-to video

It is a little messy operation. Applying oil-based rustproofing with rust inhibitors for cars and trucks means getting your car raised in the air then applying the spray to the underside of the vehicle. The mechanics of this means you will need a jack or other device and you will be under the vehicle spraying. This isn’t for everyone So you can find a oil-based rustproofing professional to apply it for you here

It isn’t 100% . You cannot beat mother nature but you can slow her down. The range of sprays on the market suggest that the problem is big. The protection they offer really depends on how well you apply it. If you are concerned about road brine and the damage it can cause (and you should be) then you want a solution that resolves the problem. Applying oil-based rustproofing with rust inhibitors for cars and trucks can help extend the life of your  second most expensive asset.

NH oil-based rustproofing with rust inhibitors These sprays can offer varying degrees of protection. If you take a look at the reviews for our products,   You will find we have made substantial progress in extending the life of vehicles and protecting them from Road brine

 

What can you do? Oil-Based Rustproofing and how it can help?

One of the major advantages of oil-based rustproofing with rust inhibitors for cars and trucks is the fact that you are creating a barrier from moisture and Road brine. NH oil-based rustproofing with rust inhibitors you will displace moisture and cut off oxygen. Take either out of the equation and oxidation cannot occur. NH Oil Undercoating will creep and penetrate deep into the body cavities, spot welds and seems. Those areas up prone to hold moisture, unprotected and generally where rust begins.

 

NH Oil Vehicle Undercoating®  has corrosion inhibitors that will remain present throughout the year. Look for oil-based rustproofing to deliver you an effective solution that can extend the life of the vehicle.

If you don’t want to trap moisture, then you will need to steer clear of rubberized undercoating for cars and trucks and look for oil based rustproofing instead. This is an application of an oil based rustproofing product that coats the underside of the vehicle – protecting all of that metal from the effects of corrosion from road brine. Unlike the other solutions, NHOU oil based rustproofing will protect fully and leave your vehicle safe from the potential threat of corrosion.

Road brine is a problem that is only just rearing its head in the consciousness of the general public. But it is a massive potential problem that can change the way your car or truck performs or provides safety. Don’t take a risk with the safety of your vehicle when it is on the road. There is far too much at stake. Look at oil based rustproofing to deal with this issue and put you in the best place possible.

 

When it comes to auto corrosion prevention… We’ve got you covered! 

See the difference for yourself!

All our specialized products will protect your vehicle against auto corrosion damage caused by salt, liquid de-icing and winter driving conditions. They are designed to penetrate the seams and crevices. It eliminates moisture. It actually stops rust and corrosion in all metals, (when present) it protects vinyl and plastic surfaces from UV rays and improves the function of moving parts through lubrication.

The fact is, a new vehicle is subjected to thousands of spot welds and numerous bends and folds during production.
This process damages the pre-coated metal, allowing exposure to the corrosion process. Besides cosmetic damage, corrosion also weakens a vehicle’s structural integrity and can affect steering and suspension components.

NH Oil Vehicle Undercoating® Services & products, undercoating for cars & trucks will perform because we use the products that we create, we have a unique opportunity to not only see the performance, but to design the products to be user-friendly.

The only product on the market formulated by the people who apply it; from us to you!

NH Oil Undercoating for Trucks & cars

 

 

 

Corrosion-Rust inhibitors for cars and truck in depth;

 

Corrosion rust Inhibitors – Principles, Mechanisms and

Applications

Camila G.  Dariva and Alexandre F.  Galio

Additional information is available at the end of the chapter http://dx.doi.org/10.5772/57255

1.  Introduction

Corrosion processes are responsible for numerous losses mainly in the industrial scope. It is clear that the best way to combat it is prevention.

Among the various methods to avoid or prevent destruction or degradation of metal surface, the corrosion inhibitor is one of the best know methods of corrosion protection and one of the most useful on the industry. This method is following stand up due to low cost and practice method. [1] [2] [3] [4]

Important researches have being conducted with government investment mainly in large areas such as development construction of new pipelines for shale gas and growth in construction. The focus of these researches has being the inhibitors applications in water and concrete for the protection of metals. [5]

Historically, inhibitors had great acceptance in the industries due to excellent anti-corrosive proprieties. However, many showed up as a secondary effect, damage the environment. Thus the scientific community began searching for friendly environmentally inhibitors, like the organic inhibitors. [6] [7] [8] [9] [10] [11] [12] [13]

This chapter presents a revision of the corrosion inhibitors applications mainly the novel compositions environmentally friendly. Is describes the mechanisms of action of inhibitors, main characteristics, environmental impact, technical analysis and calculation of efficiency.

1.1.  Mechanisms of actions of Rust inhibitors

Inhibitors are substances or mixtures that in low concentration and in aggressive environment inhibit, prevent or minimize the corrosion. [2]

© 2014 Dariva and Galio; licensee InTech. This is a paper distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Generally the mechanism of the inhibitor is one or more of three that are cited below:

  • the inhibitor is chemically adsorbed (chemisorption) on the surface of the metal and forms a protective thin film with inhibitor effect or by combination between inhibitor ions and metallic surface;
  • the inhibitor leads a formation of a film by oxide protection of the base metal;
  • the inhibitor reacts with a potential corrosive component present in aqueous media and the product is a complex. [4] [14] [15]

1.2.  Historic review of rust inhibitors

There are many industrial systems and commercial applications that inhibitors are applicable, such as cooling systems, refinery units, pipelines, chemicals, oil and gas production units, boilers and water processing, paints, pigments, lubricants, etc. [16]

There are evidences of the use of inhibitor since the early XIX century. On that time they were already used to protect metals in processes such as acid picking, protection against aggressive water, acidified oil wells and cooling systems. Since years 1950’s and 1960’s, there was significant advances in the development of technology for corrosion inhibitor as the application of electrochemistry to evaluate corrosion inhibitors. [17]

Recent studies estimate that the U.S. demand for corrosion inhibitors will rise 4.1% per year to USD$ 2.5 billion in 2017. In 2012 they estimated that the market demand of inhibitors was divided on 26.6% to refining petroleum, 16.9% utilities, 16.7% gas and oil production, 15.3% chemical, 9.5% metals, 7.1% pulp and paper and 8.0% other. [5]

Now a days, due to changes occurred on the market of corrosion inhibitors, some industrial corrosion inhibitors are being unused. Due to high toxicity of chromate, phosphate and arsenic compounds, related to various environmental and health problems, strict international laws were imposed. Reducing the use of these and therefore increasing the need for the development of other inhibitor to supply the lack in this area. Should, however, present a similar anti corrosive properties similar than a chromate inhibitor. [18]

An important number of papers have been published with the intention of develop an environmentally friendly corrosion inhibitors and a lot of research has been doing to development of the called “green” corrosion inhibitors.[19] Also, has been increasing research in natural products, such as plant extracts, essential oils and purified compounds to obtain environmentally friendly corrosion inhibitors. [20]

The first evidence of natural product use as corrosion inhibitors is 1930’s. When extracts of Chelidonium majus (Celadine) and other plants were used on the first time in H2SO4 pickling baths. Successful developments of researches to obtain natural corrosion inhibitors are growing as quickly as the environmental consciousness is gaining ground.[21]

Chromates as active inhibitors are being replaced by other components such as molybdate compounds and rare earth metal salt, like cerium chloride. Also, drugs have been studied as corrosion inhibitors. [22] [23] [24]

2. Rust Inhibitors classifications

classified by:

  • the chemical nature as organic or inorganic;
  • the mechanism of action as anodic, cathodic or a anodic-cathodic mix and by adsorption action, or;
  • as oxidants or not oxidants. [4]

In general, the inorganic inhibitors have cathodic actions or anodic. The organics inhibitors have both actions, cathodic and anodic and the protective by a film adsorption.

This chapter is subdivided in according to the classification of the inhibitors shown on the Figure 1 The corrosion inhibitors can be chemicals either synthetic or natural and could be

Figure 1. Classification of inhibitors

2.1.  Inorganic rust inhibitors

2.1.1.  Anodic rust inhibitors

Anodic inhibitors (also called passivation inhibitors) act by a reducing anodic reaction, that is, blocks the anode reaction and supports the natural reaction of passivation metal surface, also, due to the forming a film adsorbed on the metal. In general, the inhibitors react with the corrosion product, initially formed, resulting in a cohesive and insoluble film on the metal surface. [4] [24]

Figure 2 shows a potentiostatic polarization diagram of a solution with behavior inhibitor anodic. The anodic reaction is affected by the corrosion inhibitors and the corrosion potential of the metal is shifted to more positive values. As well, the value of the current in the curve decreases with the presence of the corrosion inhibitor.

Figure 2. Potentiostatic polarization diagram: electrochemical behavior of a metal in a solution with anodic inhibitor (a) versus without inhibitor (b).

The anodic inhibitors reacts with metallic ions Men+ produced on the anode, forming generally, insoluble hydroxides which are deposited on the metal surface as insoluble film and impermeable to metallic ion. From the hydrolysis of inhibitors results in OH ions. [4] Figure 3 shows how is the mechanism of the anodic inhibitory effect.

Figure 3. Illustration of anodic inorganic inhibitors effect and their mechanism of action.

When the concentrations of inhibitor becomes high enough, the cathodic current density at the primary passivation potential becomes higher than the critical anodic current density, that is, shift the potential for a noble sense, and, consequently, the metal is passivated. [25] [26]

For the anodic inhibitors effect, it is very important that the inhibitor concentrations should be high enough in the solution. The inappropriate amount of the inhibitors affects the formation of film protection, because it will not cover the metal completely, leaving sites of the metal exposed, thus causing a localized corrosion. [4] [25] [26]

Concentrations below to the critical value are worse than without inhibitors at all. In general can cause pitting, due reduction at the anodic area relative to cathodic, or can accelerate corrosion, like generalized corrosion, due to full breakdown the passivity. [25]

Some examples of anodic inorganic inhibitors are nitrates, molybdates, sodium chromates, phosphates, hydroxides and silicates.

2.1.2.  Cathodic rust inhibitors

During the corrosion process, the cathodic corrosion inhibitors prevent the occurrence of the cathodic reaction of the metal. These inhibitors have metal ions able to produce a cathodic reaction due to alkalinity, thus producing insoluble compounds that precipitate selectively on cathodic sites. Deposit over the metal a compact and adherent film, restricting the diffusion of reducible species in these areas. Thus, increasing the impedance of the surface and the diffusion restriction of the reducible species, that is, the oxygen diffusion and electrons conductive in these areas. These inhibitors cause high cathodic inhibition. [4] [24] [27]

The Figure 4 shows an example of a polarization curve of the metal on the solution with a cathodic inhibitor. When the cathodic reaction is affected the corrosion potential is shifted to more negative values.

Figure 4. Potentiostatic polarization diagram: electrochemical behavior of the metal in a cathodic inhibitors solution (a), as compared to the same solution, without inhibitor (b).

The cathodic inhibitors form a barrier of insoluble precipitates over the metal, covering it. Thus, restricts the metal contact with the environment, even if it is completely immersed, preventing the occurrence of the corrosion reaction. Due to this, the cathodic inhibitor is independent of concentration, thus, they are considerably more secure than anodic inhibitor. The Figure 5 shows the illustration of mechanical effect of cathodic inhibitors to restrain the corrosion process. [4]

Figure 5. Illustration has shown the mechanism of actuation of the cathodic inhibitors.

Some examples of inorganic cathodic inhibitors are the ions of the magnesium, zinc, and nickel that react with the hydroxyl (OH) of the water forming the insoluble hydroxides as (Mg(OH)2, Zn(OH)2, Ni(OH)2) which are deposited on the cathodic site of the metal surface, protecting it. [4] Also can be cited polyphosphates, phosphonates, tannins, lignins [15] and calcium salts as examples that presents the same reaction mechanism.

It seen in hard waters a kind of this mechanism of inhibiting, due to the effect of the magnesium or calcium bicarbonate on it. When temporary hard water flows over the metal it can assist on the nucleation of carbonates, allowing the reactions near to the equilibrium and forming precipitations on the metal surface. These precipitations, like a CaCO3, cover the cathodic area, protecting the metal. So these cathodic inhibitor depends only on the chemistry of the water, is not due the metal composition, because of this they are applicable to all metals. [4] [25]

As example, may be mentioned the oxides and salts of antimony, arsenic and bismuth, which are deposited on the cathode region in acid solutions. These cathodic inhibitors minimize the release of hydrogen ions due to a phenomena that can difficult the discharge of the hydrogen, called overvoltage.

2.2.  Organic rust inhibitor

Organic compounds used as inhibitors, occasionally, they act as cathodic, anodic or together, as cathodic and anodic inhibitors, nevertheless, as a general rule, act through a process of surface adsorption, designated as a film- forming. Naturally the occurrence of molecules exhibiting a strong affinity for metal surfaces compounds showing good inhibition efficiency and low environmental risk. [28] These inhibitors build up a protective hydrophobic film adsorbed molecules on the metal surface, which provides a barrier to the dissolution of the metal in the electrolyte. They must be soluble or dispersible in the medium surrounding the metal. [4]

In the Figure 6, that shows a theoric potentiostatic polarization curve, it can be seen that the effect of the solution containing organic inhibitor on the metal presents an anodic and cathodic behavior. After the addition of the inhibitor, the corrosion potential remains the same, but the current decreases from Icor to I’cor.

Figure 6. Theoretical potentiostatic polarization diagram: electrochemical behavior a metal on a solution containing a cathodic and anodic inhibitor (a) compared to the same solution without the inhibitor (b).

Is showed in Figure 7 the mechanism of actuation of organic inhibitors, when it is adsorbed to the metal surface and forms a protector film on it.

Figure 7. Illustration of the mechanism of actuation of the organic inhibitor: acting through adsorption of the inhibitor on the metal surface. Where the Inh represents the inhibitor molecules.

The efficiency of an organic inhibitor depends of the:

  • chemical structure, like the size of the organic molecule;
  • aromaticity and/or conjugated bonding, as the carbon chain length;
  • type and number of bonding atoms or groups in the molecule (either π or σ);
  • nature and the charges of the metal surface of adsorption mode like bonding strength to metal substrate;
  • ability for a layer to become compact or cross-linked,
  • capability to form a complex with the atom as a solid within the metal lattice;
  • type of the electrolyte solution like adequate solubility in the environment. [16]

The efficiency of these organic corrosion inhibitors is related to the presence of polar functional groups with S, O or N atoms in the molecule, heterocyclic compounds and pi electrons, generally have hydrophilic or hydrophobic parts ionizable. The polar function is usually regarded as the reaction center for the establishment of the adsorption process.[4] [28]

The organic acid inhibitor that contains oxygen, nitrogen and/or sulfur is adsorbed on the metallic surface blocking the active corrosion sites. Although the most effective and efficient organic inhibitors are compounds that have π-bonds, it present biological toxicity and environmental harmful characteristics. [29]

Due to the metal surface covered is proportional to the inhibitor concentrates, the concentrations of the inhibitor in the medium is critical. [24] [30]

Some examples are amines, urea, Mercaptobenzothiazole (MBT), benzotriazole e toliotriazol, aldehydes, heterocyclic nitrogen compounds, sulfur-containing compounds and acetylenic compounds and also ascorbic acid, succinic acid, tryptamine, caffeine and extracts of natural substances. [4] [25] [28]

There are still some inhibitors that act in vapor phase (volatile corrosion inhibitor). Some examples are: dicicloexilamônio benzoate, diisopropylammonium nitrite or benzoate, ethanolamine benzoate or carbonate and also the combination of urea and sodium nitrite. [4] [24]

3.  Techniques for analysis of rust inhibitors

The most usefully technique to analysis the effectiveness of an inhibitor are weight loss experiment and electrochemical measurements, like polarization curve method and the impedance measurement analyzing. In addition, microscopy techniques are used to characterize the corrosion process.

4.  Considerations to employ rust inhibitors

For all types of inhibitors, we should consider some environmental actions factors because some elements such as metals, pH, composition, impurities, agitation, temperature, geometry of the system, the concentration of inhibitor and the mixture of one or more inhibitors may change the anti-corrosive mechanism. [4] [23] [31] [33]

To employment of the inhibitors is quite satisfying that certain factors should be seen as the real cause of the corrosion, the cost X benefit and possible interactions of the inhibitor with the environment, such as the influence of a catalyst, deposition or contamination. Four fundamental aspects must be analyzed to obtain a satisfactory result from the use of the inhibitor.

5.  Rust inhibitor efficiency

The inhibitor efficiency could be measured by the follow equation:

Ri Ro ´100                                                                    (1)

E =f

Ro

where, Ef is inhibitor efficiency (percentage), Ri is corrosion rate of metal with inhibitor and Ro is corrosion rate of metal without inhibitor.[38]

6.  Industrial application

Acid pickling: Prevent the attack in the metal due to the acid solution in which metal gets cleaned of mill scale (bark lamination), and also prevented the subsequent hydrogen evolution inhibitors are added, typically organic, must be soluble or dispersed in the solution. Examples: thiourea and amino and its derivatives, propargyl alcohol. [4]

Oil industry: sodium carbonates or organic amines complex are employed to reduce the corrosive effect of CO2, H2S and organic acids, enabling the use of more cheaper materials and less resistant to corrosion in wells extracting crude oil. Pipes for gasoline and kerosene are employed sulphonated oils, sodium nitrite. Oil well uses up fatty amines, fatty acids, imidazolines and quaternary ammonium salts. Internal pipe corrosion occurs in wet gas transportation due to condensation of water containing dissolved corrosive gases. Corrosion is caused by the dissolution of the corrosive gases, such as carbon dioxide and hydrogen sulfide as well as condensation of acid vapors [42].

Water transmission and distribution systems: is used corrosion inhibitor in combination with pH adjusters and alkalinity control towards an efficient protection [32] The most common inhibitors are phosphates, amines volatiles (cyclohexylamine, morphine) [4]

Concrete: To improve the durability of reinforced concrete structures, which are impaired due the high alkalinity, are used corrosion inhibitors, mixed with cement or concrete paste. An example is phosphate ion. [33]

Boiler: Thermoelectric use, in general, Ammonia, Cyclohexylamine, alkanol and Morpholine as inhibitors in boilers in various processes. The inhibitors, also, are added by the hydrochloric acid used for the solubilization of limescale to prevent the attack on pipes.

7.  Conclusion

Inhibitors are a great method of preventing corrosion and are easy to apply. Has application in a wide range of sectors

The knowledge of the method of the action, facilitates the choice of the inhibitors, improves efficiency, avoids the process is impaired and side effects.

It is important in the choice of inhibitor, ascertain the subsequent effects of this towards the environment.

The search for environmental friendly inhibitors has shown excellent results, outperforming conventional inhibitors.

Reference organic inhibitors newly developed

7 K2Cr2O7 10-4 M 97.31
7 Cerium

dibutylphosphate (Ce(dbp)3)

10-4 M 94.10

AA2024-T3                                                       0,1 M NaCl[23]

7 Cerium chloride (CeCl3) 10-4 M 73.90
AA5754 3% NaCl 6.3 Laurus nobilis L. oil 50ppm 84.3 [43]
Al 3% NaCl 6.3 Laurus nobilis L. oil 50ppm 89.9 [43]
AA5083 3.5% NaCl 5.5 CeCl3 500ppm 297 [44]
LaCl3 500ppm 113 [44]
Steel 1M HCl N. cadamba Bark extract 5mgL-1 91.0 [45]
Steel 1 M HCl VSBH (C31H47O4N2Br) 400 ppm 95.0 [46]
Steel 88% phosphoric acid Dried Zenthoxylum-alatum

plant fruits

2400ppm 98.0 [47]
Steel 0.5 M H2SO4 Polyacrylamide grafted Okra mucilage(O-g-PAM) 100ppm 94.4 [48]
Copper 0.5M HCl Chitosan 8 × 10−6 92.0 [29]
Cu-10Al-5Ni alloy 3.5% NaCl Cysteine 6mM/L 96.0 [49]
N-acetylcysteine 6mM/L 87.6 [49]
alloy environmental pH inhibitor concentration efficiency reference
Methionine 6mM/L 76.7 [49]
Cu 0.6M NaCl Cysteine 16mM 76.5 [50]
Cu 1M HCl Cysteine 18mM 84.13 [50]
AZ91D 0.05 wt.% NaCl 9 Paeonol 50ppm by wt 90 [51]
AZ91D ASTM D1384-87 8.2 8-hydroxyquinoline Saturated with

8HQ

82 [52]
AZ91D alloy 0.05 wt.% NaCl 6.8 5,10,15,20-

tetraphenylporphyrin (TPP)

5ppm 84 [53]

Table 1. Inhibitors organics for aluminum, steel, copper, magnesium and its alloys at room temperature.

Author details

Camila G.  Dariva and Alexandre F.  Galio*

*Address all correspondence to: afgalio@ufrgs.br

PPEng – CAPES and Universidade Federal do Pampa Bagé/RS, Brazil

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